I'm novice with the XACML world. I've read some documentation regarding JSON and REST profiles of the v3.0 standard but everything I can find is related to XACML requests and responses and not policies (which is the part I'm interested in).
Is there any documentation about how should XACML policies be defined using a JSON profile instead of the traditional XML format?
No there isn't at the moment. The JSON profile of XACML only deals with XACML requests and responses. The idea behind the profile is to provide a more lightweight way of sending and receiving XACML requests / responses.
Since policies are typically at rest, the encoding of the policy doesn't matter so much.
That said, there are 3 initiatives you may be interested in: