I wonder is there any way to slice this sprite(dialog pop up thing) that could keep the bottom center (the upside-down triangle) not scaled? I'm using nGUI if it matters.
Sorry, but that's how 9-slice scaling works. You would need 25 slice scaling to do what you're looking for and that's overkill for most things, so I've never seen an implementation.
Break up your sprite into two pieces: the 9-slice portion and the "notch" portion. Then just position the notch to be in the right place.
I haven't used nGUI (only iGUI and the Unity native--both old and new) so I'm not sure on the precise nature of how nGUI will let you do that, but you'd still need two sprites, one of which is scaled and the other one which isn't, positioned either manually or through parent-child relative relationship. If your dialog is always the same width, it'll be pretty straight forward. If not, it might be more challenging.
A few other things:
You'll probably want the notch sprite and the bubble sprite to the same native image size, but its not necessary (might make things easier, might not).
The notch will want to have some "overbleed" so that when the two stack the underlying rendering code doesn't go all squinty eyed and go "there's a gap here..." and draw through in some cases.
Depending on the bubble portion's drawn edge, you might want the notch to be in front or behind. In your precise case, I don't think it'll make a difference. It's a little hard to tell due to the colors, but when I did a selectable tab (which is built similarly), the tab sits on top of the container window so that the shaded edge flows nicely. The unselected version then has no overbleed so it looks like it sits "behind" (accurate pixel placement--2D game at a fixed size--insures that no "gap" is rendered).