Because PHP-Excel is deprecated, PHP-Spreadsheet is the new Option to make Excel in PHP. The Documentation is not the best and the're not many questions on Stackoverflow about PHP-Spreadsheet, so that's why I make this Question about how to make the first row bold in PHP-Spreadsheet.
This should do the trick.
//Create Spreadsheet
$spreadsheet = new Spreadsheet();
$sheet = $spreadsheet->getActiveSheet();
//Create Styles Array
$styleArrayFirstRow = [
'font' => [
'bold' => true,
]
];
//Retrieve Highest Column (e.g AE)
$highestColumn = $sheet->getHighestColumn();
//set first row bold
$sheet->getStyle('A1:' . $highestColumn . '1' )->applyFromArray($styleArrayFirstRow);