I've got a table that looks a bit like this
What I want to do is find the pressure value of the earliest Start_Time
So in this case I want the value "5"
How can I do this? I'm not sure of how to relate 2 values this way
You want the first value by start_time so sort by start_time and take the first one:
Select top 1 Pressure, Start_Time
From yourTable
Order by Start_Time asc