No you have 63 columns. You have multiple times 39 (x7) and 45 (x8)
Try:
>>> len(df.columns)
Remove the prefix number of the question to be not confused:
df.columns = df.columns.str.replace('^\d+\.\s+', '')
Some questions are the same:
'39. How much debt does your household have? [Car loans]',
'39. How much debt does your household have? [Credit Cards]',
'39. How much debt does your household have? [Medical Loans]',
'39. How much debt does your household have? [Mortgages]',
'39. How much debt does your household have? [Payday Loans]',
'39. How much debt does your household have? [Student Loans]',
'39. How much debt does your household have? [Other]',
'45. Please tell us how satisfied you are with each of these following aspects of your present job [Earnings]',
'45. Please tell us how satisfied you are with each of these following aspects of your present job [Benefits]',
'45. Please tell us how satisfied you are with each of these following aspects of your present job [Job security]',
'45. Please tell us how satisfied you are with each of these following aspects of your present job [Work-life balance]',
'45. Please tell us how satisfied you are with each of these following aspects of your present job [Professional growth or leadership opportunities]',
'45. Please tell us how satisfied you are with each of these following aspects of your present job [Workplace/company culture]',
'45. Please tell us how satisfied you are with each of these following aspects of your present job [Diverse and inclusive work environment]',
'45. Please tell us how satisfied you are with each of these following aspects of your present job [Weekly workload]',