For my Azure App Service I have Minimum Inbound TLS Cipher Suite set to TLS_RSA_WITH_AES_128_CBC_SHA.
For my App Service it is:

I know that I can change it manually via App service -> Configuration
but is there any az command to change it programmatically?
You can configure the Minimum Inbound TLS Cipher Suite programmatically using Azure CLI.
Instead of setting it manually in App Service → Configuration → General Settings, you can apply it directly like this:
az webapp config set \
--resource-group <resource-group-name> \
--name <app-service-name> \
--min-tls-cipher-suite TLS_RSA_WITH_AES_128_CBC_SHA
This updates the App Service to require the specified minimum cipher suite.
Official docs for reference:
Azure CLI webapp config → https://learn.microsoft.com/cli/azure/webapp/config
TLS Cipher configuration background → https://azure.github.io/AppService/2022/10/11/Public-preview-min-tls-cipher-suite.html