I'm using Segment Plot to show multiple lines on the chart. How can I make these lines have arrows on their ends?
You can do this with some SVG + DOM hacking. You can define a "marker element" that can be placed at the beginning, middle or end of a line (see http://tutorials.jenkov.com/svg/marker-element.html for details on markers).
This means manipulating the SVG generated by Plottable. To get the underlying DOM elements, you need to get hold of the d3 "selection" representing each line.
<svg>
element where you are rendering the plot. I am pretty sure plottable won't overwrite entities already inside, but if it does you can always add it after rendering the plot.