The ZIP file format supports a number of compression algorithms and assigns them numbers, for example 0 is store, 8 is deflate, and 14 is lzma. What number indicates Brotli compression? Is there any additional zip-level metadata needed for this compression algorithm?
As of this writing, there isn't one. The official list of ZIP file format compression methods is found in PKWare's ZIP Appnote, for which the most recent version is 6.3.4, dated October 1, 2014. Here are the defined compression methods therein:
4.4.5 compression method: (2 bytes)
0 - The file is stored (no compression)
1 - The file is Shrunk
2 - The file is Reduced with compression factor 1
3 - The file is Reduced with compression factor 2
4 - The file is Reduced with compression factor 3
5 - The file is Reduced with compression factor 4
6 - The file is Imploded
7 - Reserved for Tokenizing compression algorithm
8 - The file is Deflated
9 - Enhanced Deflating using Deflate64(tm)
10 - PKWARE Data Compression Library Imploding (old IBM TERSE)
11 - Reserved by PKWARE
12 - File is compressed using BZIP2 algorithm
13 - Reserved by PKWARE
14 - LZMA (EFS)
15 - Reserved by PKWARE
16 - Reserved by PKWARE
17 - Reserved by PKWARE
18 - File is compressed using IBM TERSE (new)
19 - IBM LZ77 z Architecture (PFS)
97 - WavPack compressed data
98 - PPMd version I, Rev 1
I suppose you could define your own method number and use it, but that use would be non-standard. (It is a two-byte field, so you could pick a large number that PKWare would be very unlikely to define to be something else.)
No, there is no other information required to be able to decompress a brotli stream.
Update:
As of the July 2020 appnote (6.3.9), more compression methods, notably zstd and xz, but still no brotli.
4.4.5 compression method: (2 bytes)
0 - The file is stored (no compression)
1 - The file is Shrunk
2 - The file is Reduced with compression factor 1
3 - The file is Reduced with compression factor 2
4 - The file is Reduced with compression factor 3
5 - The file is Reduced with compression factor 4
6 - The file is Imploded
7 - Reserved for Tokenizing compression algorithm
8 - The file is Deflated
9 - Enhanced Deflating using Deflate64(tm)
10 - PKWARE Data Compression Library Imploding (old IBM TERSE)
11 - Reserved by PKWARE
12 - File is compressed using BZIP2 algorithm
13 - Reserved by PKWARE
14 - LZMA
15 - Reserved by PKWARE
16 - IBM z/OS CMPSC Compression
17 - Reserved by PKWARE
18 - File is compressed using IBM TERSE (new)
19 - IBM LZ77 z Architecture
20 - deprecated (use method 93 for zstd)
93 - Zstandard (zstd) Compression
94 - MP3 Compression
95 - XZ Compression
96 - JPEG variant
97 - WavPack compressed data
98 - PPMd version I, Rev 1
99 - AE-x encryption marker (see APPENDIX E)