I was reading about JSF that it's a UI framework and provides some UI components. But how is it better or different from number of components that are available from jQueryUI, AngularJS, React, Vue.js, Svelte, ExtJS, or even plain HTML, CSS and JavaScript.
Why should someone learn JSF?
JSF to plain JSP/Servlet/HTML/CSS/JS is like as jQuery to plain JS: do more with less code. To take PrimeFaces (jQuery + jQuery UI based) as an example, browse through its showcase to see complete code examples. BootsFaces (jQuery + Bootstrap UI based) has also a showcase with complete code examples. If you study those examples closely, then you'll see that you basically need a simple Javabean class as model and a XHTML file as view.
Note that you should not see JSF as replacement of alone HTML/CSS/JS, you should also take the server side part into account (specifically: JSP/Servlet). JSF removes the need of all the boilerplate of gathering HTTP request parameters, converting/validating them, updating the model values, executing the right Java method to do the business stuff and generating the HTML/CSS/JS boilerplate code. With JSF you basically end up with a XHTML page as view definition and a Javabean class as model definition. This greatly speeds up development.
As with every component based web MVC framework, you have in JSF less fine-grained control over the rendered HTML/CSS/JS. Adding custom JS code isn't that easy as you have to take the JSF view state in the server side into account as well (e.g. enabling a disabled button in JS side won't enable the button in JSF side, which is in turn a huge security advantage). If that is however a major showstopper, then rather look for an action based web MVC framework like Spring MVC. You'll only take into account that you have to write all that HTML/CSS/JS code (and prevention against XSS, CSRF and DOM-manipulation!) yourself. Also if you fall back from Facelets to JSP, you'll miss advanced templating capabilities as well.
On the other hand, if you have a big JSP/Servlet/HTML/CSS/JS/jQuery based website and you'd like to refactor the repeated JSP/Servlet/HTML/CSS/JS/jQuery boilerplate code into reusable components, then one of the solutions would be JSF. Custom templates, tagfiles and components can aid in this. In that perspective, JSF stands above JSP/Servlet/HTML/CSS/JS/jQuery (and that's also why it's pretty important to understand those basics before diving into JSF).
You can find a real world kickoff JSF based project here: Java EE Kickoff App. You'll see that it contains next to JSF as good HTML5, CSS3 and jQuery.